Additive manufacturing of SiBCN/Si₃N₄w composites from preceramic polymers by digital light processing

The application of advanced ceramic materials is limited by their brittleness and complicated manufacturing methods. Three-dimensional (3D) printing has emerged as a new method for the fabrication of complex-shaped ceramics. Herein, a type of printable slurry composed of SiBCN preceramic polymers and high-volume fractions of Si₃N₄ whiskers (up to 60 wt% of polymer) was prepared, and subsequently printed via digital light processing (DLP) technology. We successfully manufactured complex-structured ceramic composites and achieved high bending strength (∼180 MPa). The linear shrinkage and mass loss of the ceramic material were both significantly reduced after the introduction of whiskers. The properties and structure of the printed parts pyrolyzed at different temperatures were compared, and the relationship between the microstructure and mechanical properties discussed.