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A boronization-induced amorphous-crystalline interface on a Prussian blue analogue for efficient and stable seawater

Yikang Wang1, Dongmei Jia1, Wenyao Zhang1

  • 1College of Material, Chemistry and Chemical Engineering, Key Laboratory of Organosilicon Chemistry and Material Technology, Ministry of Education, Hangzhou Normal University, Hangzhou, 311121, China. gjia@hznu.edu.cn.

Chemical Communications (Cambridge, England)
|May 4, 2022
PubMed

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Hydroboration-Oxidation of Alkenes03:08

Hydroboration-Oxidation of Alkenes

In addition to the oxymercuration–demercuration method, which converts the alkenes to alcohols with Markovnikov orientation, a complementary hydroboration-oxidation method yields the anti-Markovnikov product. The hydroboration reaction, discovered in 1959 by H.C. Brown, involves the addition of a B–H bond of borane to an alkene giving an organoborane intermediate. The oxidation of this intermediate with basic hydrogen peroxide forms an alcohol.