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Updated: Sep 24, 2025

Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes
Published on: November 21, 2017
Retracted Article: Metal-free [2+2+1] cycloaddition polymerization of alkynes, nitriles, and oxygen atoms to
Lichao Dong1, Tian Lan1, Yin Liang1
1The 306th Institute of China Aerospace Science & Industry Corp. Beijing 100074 China 610557405@qq.com.
Abstract:
The metal-free [2+2+1] cycloaddition polymerization of alkynes, nitriles, and O-atoms for the regioselective assembly of highly substituted oxazole compounds has been achieved by the use of iodosobenzene (PhIO) with trifluoromethanesulfonic acid (TfOH). The present reaction could be applied to a facile synthesis of polyoxazoles. In this work, the cycloaddition polymerization of 4-cyano-4'-ethynylbiphenyl and PhIO was developed and modified polyoxazole was prepared. All experimental conditions such as polymerization solvent, temperature, catalyst and time were systematically studied. The structure of the obtained polyoxazole was characterized by GPC and NMR, and its thermal properties were studied by TGA. In addition, the good thermal stability of polyoxazoles with unreacted terminal alkynes and cyano groups makes them potentially useful for modifying resins.
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