O₂ activation by core-shell Ru₁₃@Pt₄₂ particles in comparison with Pt₅₅ particles: a DFT study

The reaction of O₂ with a Ru₁₃@Pt₄₂ core-shell particle consisting of a Ru₁₃ core and a Pt₄₂ shell was theoretically investigated in comparison with Pt₅₅. The O₂ binding energy with Pt₅₅ is larger than that with Ru₁₃@Pt₄₂, and O-O bond cleavage occurs more easily with a smaller activation barrier (E _a) on Pt₅₅ than on Ru₁₃@Pt₄₂. Protonation to the Pt₄₂ surface followed by one-electron reduction leads to the formation of an H atom on the surface with considerable exothermicity. The H atom reacts with the adsorbed O₂ molecule to afford an OOH species with a larger E _a value on Pt₅₅ than on Ru₁₃@Pt₄₂. An OOH species is also formed by protonation of the adsorbed O₂ molecule, followed by one-electron reduction, with a large exothermicity in both Pt₅₅ and Ru₁₃@Pt₄₂. O-OH bond cleavage occurs with a smaller E _a on Pt₅₅ than on Ru₁₃@Pt₄₂. The lower reactivity of Ru₁₃@Pt₄₂ than that of Pt₅₅ on the O-O and O-OH bond cleavages arises from the presence of lower energy in the d-valence band-top and d-band center in Ru₁₃@Pt₄₂ than in Pt₅₅. The smaller E _a for OOH formation on Ru₁₃@Pt₄₂ than on Pt₅₅ arises from weaker Ru₁₃@Pt₄₂-O₂ and Ru₁₃@Pt₄₂-H bonds than the Pt₅₅-O₂ and Pt₅₅-H bonds, respectively. The low-energy d-valence band-top is responsible for the weak Ru₁₃@Pt₄₂-O and Ru₁₃@Pt₄₂-OH bonds. Thus, the low-energy d-valence band-top and d-band center are important properties of the Ru₁₃@Pt₄₂ particle.