Alkali modified P25 with enhanced CO₂ adsorption for CO₂ photoreduction

To improve the CO₂ adsorption on the photocatalyst, which is an essential step for CO₂ photoreduction, solid solutions were fabricated using a facile calcination treatment at 900 °C. Using various alkalis, namely NaOH, Na₂CO₃, KOH, K₂CO₃, the resulted samples presented a much higher CO₂ adsorption capacity, which was measured with the pulse injection of CO₂ on the temperature programmed desorption workstation, compared to the pristine Evonik P25. As a result, all of the fabricated solid solutions produced higer yield of CO under UV light irradiation due to the increased basicity of the solid solutions even though they possessed only the rutile polymorph of TiO₂. The highest CO₂ adsorption capacity under UV irradiation was observed in the sample treated with NaOH, which contained the highest amount of isolated hydroxyls, as shown in the FTIR studies.