Controllable TiO₂ coating on the nickel-rich layered cathode through TiCl₄ hydrolysis via fluidized bed chemical...

Surface coating of metal oxides is an effective approach for enhancing the capacity retention of a nickel-rich layered cathode. Current conventional coating techniques including wet chemistry methods and atomic layer deposition are restricted by the difficulty in perfectly balancing the coating quality and scale-up production. Herein, a highly efficient TiO₂ coating route through fluidized bed chemical vapor deposition (FBCVD) was proposed to enable scalable and high yield synthesis of a TiO₂ coated nickel-rich cathode. The technological parameters including coating time and TiCl₄ supply rate were systematically studied, and thus a utility TiO₂ deposition rate model was deduced, promoting the controllable TiO₂ coating. The FBCVD TiO₂ deposition mechanism was fundamentally analyzed based on the TiCl₄ hydrolysis principle. The amorphous and uniform TiO₂ coating layer is compactly attached on the particle surface, forming a classical core-shell structure. Electrochemical evaluations reveal that the TiO₂ coating by FBCVD route indeed improves the capacity retention from 89.08% to 95.89% after 50 cycles.