Synthesis and characterization of low density porous nickel zinc ferrites

Ni-Zn ferrite has important applications in the field of soft magnetic materials due to its excellent magnetic properties, but its high bulk density hinders its promotion. Herein, an oxalate precursor was prepared by a coprecipitation method with metal sulfate and oxalic acid as raw materials. The low density porous Ni-Zn ferrite powder was prepared by thermal decomposition in an aerobic environment with the oxalate precursor. The microstructure, morphology, and dielectric and magnetic properties of Ni-Zn ferrite were studied by thermogravimetric and differential scanning calorimetry, X-ray powder diffraction, X-ray photoelectron spectroscopy, Fourier transform-infrared spectroscopy, scanning electron microscopy, transmission electron microscopy, tap density testing for powder, vibrating sample magnetometry, specific surface and aperture analysis and vector network analysis. The results showed that the purity, morphology, grain size and saturation magnetization of Ni-Zn ferrite were controlled by many factors such as synthetic temperature, retaining time and environmental conditions. Under an oxygen atmosphere, pure Ni-Zn ferrite can be prepared from an oxalate precursor by a thermal process. The ferrite has a wood-splitting appearance and a multi-layered internal cavity structure, and the bulk density is only 1/3 of the general ferrite. It has good soft magnetic and microwave absorbing properties, which makes it a potential excellent material for microwave absorbers.