Efficient removal of tar employing dolomite catalyst in gasification: Challenges and opportunities

Fossil fuels are currently the dominant source of electricity and energy production around the world. Biomass is one of the most referred renewable carbonaceous resource(s) that can be employed for the waste-to-energy concept. Syngas obtained from biomass gasification can be utilized for a variety of key industrial purposes, including internal gasification engine operation, power generation, and hydrocarbon compound production using the Fisher-Tropsch technique. However, the existence of impurities such as hydrogen sulfide, tar, and particulate matter along with other undesirable chemicals present in syngas are major disadvantages of biomass gasification. Tar is the most difficult among all the pollutants to be removed from syngas; it also causes serious problems in downstream syngas applications. For decades, studies have been performed with various catalysts to remove the tar. Dolomite has shown positive response for tar elimination and hydrogen-enriched gas production. Several studies have been carried out on dolomite for eliminating the tar from syngas. This review encompasses sources of solid waste, the mechanism of catalysis, and in-situ and ex-situ usage of dolomite in the gasification process. It addresses the key issues such as fragmentation and attrition, elutriation, and coke formation along with dolomite's usefulness in amalgamation with other catalysts, environmental consequences, and economic viability of dolomite applications. It also discusses the challenges and opportunities for tar removal using catalysts, with a specific focus on dolomite along with economic and environmental sustainability considerations.