Mesoporous hollow black TiO₂ with controlled lattice disorder degrees for highly efficient visible-light-driven...

Black TiO₂ has received tremendous attention because of its lattice disorder-induced reduction in the TiO₂ bandgap, which yields excellent light absorption and photocatalytic ability. In this report, a highly efficient visible-light-driven black TiO₂ photocatalyst was synthesized with a mesoporous hollow shell structure. It provided a higher specific surface area, more reaction sites and enhanced visible light absorption capability, which significantly promoted the photocatalytic reaction. Subsequently, the mesoporous hollow black TiO₂ with different lattice disorder-engineering degrees were designed. The structure disorder in the black TiO₂ obviously increased with reduction temperature, leading to improved visible light absorption. However, their visible-light-driven photocatalytic efficiency increased first and then decreased. The highest value can be observed for the sample reduced at 350 °C, which was 2-, 1.4- and 5-fold that of the samples reduced at 320 °C, 380 °C and 400 °C, respectively. This contradiction can be ascribed to the varied functions of the surface defects with different concentrations in the black TiO₂ during the catalytic process. In particular, the defects at low concentrations boost photocatalysis but reverse photocatalysis at high concentrations when they act as charge recombination centers. This study provides significant insight for the fabrication of high-efficiency visible-light-driven catalytic black TiO₂ and the understanding of its catalysis mechanism.