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Updated: Sep 23, 2025

Fabrication of White Light-emitting Electrochemical Cells with Stable Emission from Exciplexes
Published on: November 15, 2016
Synthesis and properties of hyperbranched polymers for white polymer light-emitting diodes
Xuefeng Li1,2, Haocheng Zhao3,4, Long Gao2
1College of Materials Science and Engineering, Taiyuan University of Technology Taiyuan 030024 China xiexiaoling@tyut.edu.cn.
Abstract:
In this work, a series of hyperbranched copolymers with fluorene-alt-carbazole as the branches, three-dimensional-structured spiro[3.3]heptane-2,6-dispirofluorene (SDF) as the core, and iridium 1-(4-bromophenyl)-isoquinoline (acetylacetone) (Ir(Brpiq)2acac) as the dimming group were synthesized by one-pot Suzuki polycondensation for white emission. All copolymers show great thermal stabilities and high hole-transporting ability due to the introduction of the carbazole unit. The hyperbranched structures for copolymers can suppress the interchain interactions efficiently, and help to form amorphous films. The fabricated polymer light-emitting devices (PLEDs) based on the above synthesized copolymers realize good white light emission, and achieve high electroluminescence (EL) performance. For example, for the optimized PLED, the maximum luminance and current efficiency reach 6210 cd m-2 and 6.30 cd A-1, respectively, indicating the synthesized hyperbranched copolymers have potential application in solution-processable white polymer light-emitting diodes.
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