Simple preparation of a CuO@γ-Al₂O₃ Fenton-like catalyst and its photocatalytic degradation function

We designed a photocatalyst and developed sustainable wastewater purification technology, which have significant advantages in effectively solving the global problem of drinking water shortage. In this study, a new nanocomposite was reported and shown to be a catalyst with excellent performance; CuO was coated successively onto functionalized nano γ-Al₂O₃, and this novel structure could provide abundant active sites. We evaluated the performance of the CuO@γ-Al₂O₃ nanocomposite catalyst for polyvinyl alcohol (PVA) degradation under visible light irradiation. Under optimized conditions (calcination temperature, 450 °C; mass ratio of γ-Al₂O₃:Cu(NO₃)₂·3H₂O, 1:15; pH value, 7; catalyst dosage, 2.6 g/L; reaction temperature, 20 °C; and H₂O₂ dosage, 0.2 g/mL), the CuO@γ-Al₂O₃ nanocomposite catalyst presented an excellent PVA removal rate of 99.21%. After ten consecutive degradation experiments, the catalyst could still maintain a PVA removal rate of 97.58%, thus demonstrating excellent reusability. This study provides an efficient and easy-to-prepare photocatalyst and proposes a mechanism for the synergistic effect of the photocatalytic reaction and the Fenton-like reaction.