Compositional dependence of structures and hydrogen evolution reaction activity of platinum-group-metal quinary
Yuto Maruta1, Kohei Kusada1,2,3, Dongshuang Wu1
1Division of Chemistry, Graduate School of Science, Kyoto University, Kitashirakawa-Oiwakecho, Sakyo-ku, Kyoto 606-8502, Japan. kusada@kuchem.kyoto-u.ac.jp.
Chemical Communications (Cambridge, England)
|May 13, 2022
Abstract:
Platinum-group-metal quinary RuRhPdIrPt alloy nanoparticles were synthesised with compositions slightly away from equimolar, and their crystal and electronic structures were investigated. Their lattice constant changed linearly with composition, while the d-band centre changed nonlinearly. Their catalytic activities for the hydrogen evolution reaction were not correlated with their d-band centre.
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