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Updated: Sep 23, 2025

Sulfate Separation by Selective Crystallization with a Bis-iminoguanidinium Ligand
Published on: September 8, 2016
Solubility of sulfur dioxide in tetraglyme-NH4SCN ionic liquid: high absorption efficiency
Qiang Xu1, Wei Jiang1, Jianbai Xiao1
1College of Chemistry and Molecular Engineering, Peking University 100871 PR China xhwei@pku.edu.cn.
Abstract:
An easily prepared ionic liquid was synthesized by a one-step method and applied in SO2 absorption efficiently. The cation of the ionic liquid is a supramolecular structure consisting of NH+ 4 and tetraglyme, similar to the structure of NH+ 4 and crown ether, and the anion is selected as SCN-. The ionic liquid has good thermal stability. Under the conditions of 293 K and 1 bar, one mol ionic liquid can absorb 2.73 mol SO2, which is about 30% higher than tetraglyme. The absorption mechanism was characterized using IR and NMR. And the results confirmed that the interaction mechanism between SO2 and the ionic liquid is a physical interaction rather than a chemical interaction.
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