Nanochitosan functionalized hydrophobic starch/guar gum biocomposite for edible coating application with improved...

The current work demonstrates a unique approach of utilizing nanochitosan (NCS) based edible nanomodifier for functionalizing starch (ST)/guar gum (GG) biocomposite with superior packaging properties targeting stringent edible food packaging on fresh cuts. The effectiveness of NCS in terms of structure-property-performance analysis of ST/GG biocomposites was done. The inclusion of NCS to the biocomposites of ST/GG converts its hydrophilic surface nature to hydrophobic (contact angle of ~114°) by modifying the surface features. The addition of NCS improved the thermal stability, where the observed 10% weight degradation of ST biocomposites were ~79.36, ~80.49, and ~186.89 °C for neat ST, ST/GG biocomposites, and ST/GG/NCS (3% w/v) (ST-GG-NCS3), respectively. The observed transparency of ST, ST-GG, and ST-GG-NCS3 were 21, 8, and 48%, respectively in the visible region suggesting consumer preference for transparent packaging materials. The wt% of O, C and N elements in ST-GG-NCS3 as observed by EDX spectra were ~ 50.2, ~47.6, and ~ 2.2%, respectively, which confirm the safety of the materials. Additionally, it is noteworthy to mention that the storage quality in terms of microbial growth, pH change, color attributes, and weight loss are better preserved when used as an edible coating on cut apple fruits.