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Published on: November 21, 2017
Crystallization-Induced Redox-Active Nanoribbons of Organometallic Polymers
Jialong Wu1, Lu-Tao Weng2, Wei Qin3
1DSAP, PCFM and GDHPPC lab, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China.
Abstract:
Polymer/inorganic functional nanostructures are essential for the fabrication of high-performance nanodevices in the future. The synthesis of hybrid nanostructures is hindered by complicated synthetic protocols or harsh conditions. Herein, we report a facile and scalable method for the synthesis of organometallic polymer nanoribbons through crystallization of polymers capped with a ferrate complex. Nanoribbons consisted of a single crystalline polymer lamella coated with a redox-active ferrate complex on both sides. The nanoribbons had a width of approximately 70 nm and a thickness of 10 nm. With the merit of highly ordered crystalline structures of polymers and functional coating layers, as well as a highly anisotropic nature, the nanoribbons are useful in nanodevices and biosensors.
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