Related Experiment Video
Updated: Sep 22, 2025

Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
Published on: June 21, 2017
Synthesis of Sequence-Regulated Polymers: Alternating Polyacetylene through Regioselective Anionic Polymerization of
1The State Key Laboratory of Molecular Engineering of Polymers, Collaborative Innovation Center of Polymers and Polymer Composite Materials, Department of Macromolecular Science, Fudan University, Shanghai, 200433, China.
Abstract:
We hereby report a strategy to synthesize sequence-regulated substituted polyacetylenes using living anionic polymerization of designed monomers, that is, 2,4-disubstituted butadienes. It is found that proper substituents, such as 2-isopropyl-4-phenyl, lead to nearly 100% 1,4-addition during the polymerization, thus, giving product with high regioregularity, precise molecular weight, and narrow molecular weight distribution. The product is convertible into sequence-regulated substituted polyacetylene by oxidative dehydrogenation using 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ). Block copolymers containing polyacetylene segment are also prepared. Owing to the versatility of the anionic reactions, the present strategy can serve as a powerful tool of precise control on polymer chain microstructure, architecture, and functionalities in the same time.
More Related Videos
09:35Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
Published on: September 18, 2016
09:22Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives
Published on: February 7, 2017
Related Concept Videos
Free-Radical Chain Reaction and Polymerization of Alkenes
Anionic Chain-Growth Polymerization: Overview
Anionic Chain-Growth Polymerization: Mechanism
Olefin Metathesis Polymerization: Acyclic Diene Metathesis (ADMET)
Similar to cross-metathesis, ADMET also involves the formation of metallacyclobutane intermediate by [2+2] cycloaddition of one of the double bonds of a terminal diene with...
Preparation of Alkynes: Alkylation Reaction
Alkylation of terminal alkynes with primary alkyl halides in the presence of a strong base like sodium amide is one of the common methods for the synthesis of longer carbon-chain alkynes. For example, treatment of 1-propyne with sodium amide followed by reaction with ethyl bromide yields 2-pentyne.
Radical Chain-Growth Polymerization: Chain Branching