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Updated: Sep 22, 2025

Facile and Efficient Preparation of Tri-component Fluorescent Glycopolymers via RAFT-controlled Polymerization
Published on: June 19, 2015
RAFT Polymerization with Triphenylstannylcarbodithioates (Sn-RAFT)
Ihor Kulai1,2, Oleksii Brusylovets2, Zoia Voitenko2
1IMRCP, UMR 5623, Université de Toulouse, 118, route de Narbonne F-31062 Toulouse, Cedex 9, France.
Abstract:
A new range of tin-based reversible addition-fragmentation chain-transfer (RAFT) agents is described and evaluated for the polymerization of acrylamides, methyl acrylate and styrene. These organometallic compounds are highly reactive reversible transfer agents which allow an efficient control of the polymerization of substituted acrylamide monomers, whereas RAFT control for methyl acrylate and styrene polymerization is contaminated by side reactions at prolonged reaction times. 119Sn NMR is shown to be an informative instrument for the monitoring of Sn-RAFT-mediated polymerizations.
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