Mechanoresponsive PS-PnBA-PS Triblock Copolymers via Covalently Embedding Mechanophore

A mechanically active spiropyran (SP) mechanophore is incorporated into the center of poly(n-butyl acrylate) (PnBA) block to construct a series of mechanoresponsive polystyrene (PS)-PnBA-SP-PnBA-PS triblock copolymers. Similar mechanical activations of SP occur in all of the copolymers in solution, whereas a unique PS fraction-dependent mechanochromism is observed in the bulk. Effective mechanical activation occurs in the copolymer with a medium PS block length, whereas a very weak color change is observed in the samples bearing low PS fractions and activation appears only in the vicinity of the fracture point in the copolymer bearing long PS blocks. The difference in chemical compositions of the triblock copolymers leads to different microphase separated structures in the bulk and consequently the unique stress-strain responses and mechanochemistry. This platform promises to open way to the design of a wide range of useful mechanoresponsive triblock copolymers having different hard/soft blocks and various types of mechanoresponsive motifs.