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Facile and Rapid Access to Glyconanocapsules by CuAAC Interfacial Polyaddition in Miniemulsion Conditions
Rémi Roux1,2,3,4, Ludovic Sallet1,2,3, Pierre Alcouffe1,2,3
1Université de Lyon, Lyon, F-69003, France.
ACS Macro Letters
|May 24, 2022
Abstract:
Glyconanocapsules with a biocompatible oily core have been successfully prepared by copper(I)-catalyzed azide-alkyne cycloaddition (CuAAC) interfacial step growth polymerization between 6,6'-diazido-6,6'-dideoxysucrose and bis(propargyloxy)butane in oil-in-water miniemulsion conditions. Optimization of the interfacial polymerization process in dispersed medium afforded the rapid and reproducible preparation of stable monodispersed glyconanocapsules having a diameter around 200 nm.
