Related Experiment Video
Updated: Sep 22, 2025

Anionic Polymerization of an Amphiphilic Copolymer for Preparation of Block Copolymer Micelles Stabilized by π-π Stacking Interactions
Published on: October 10, 2016
Combination of Cationic and Radical RAFT Polymerizations: A Versatile Route to Well-Defined Poly(ethyl vinyl
Marc Guerre1, Mineto Uchiyama2, Enrique Folgado1,3
1Institut Charles Gerhardt Montpellier, Team: Ingénierie et Architectures Macromoléculaires, UMR5253, CNRS-UM-ENSCM, 8 rue de l'école Normale, 34296 Cedex 5 Montpellier, France.
Abstract:
Poly(vinylidene fluoride)-containing block copolymers are difficult to prepare and still very rare in spite of their potential use in high added value applications. This communication describes in detail the synthesis of unprecedented poly(ethyl vinyl ether)-poly(vinylidene fluoride) (PEVE-PVDF) block copolymers (BCP) via the sequential combination of cationic RAFT polymerization of vinyl ethers and radical RAFT polymerization of vinylidene fluoride (VDF). Dithiocarbamate chain transfer agents were found to efficiently control the radical RAFT polymerization of VDF and to be suitable for the preparation of PEVE-PVDF BCP. These new block copolymers composed of incompatible polymer segments may find applications owing to their phase segregation and self-assembly behavior.
More Related Videos
11:42Synthesis of Monodisperse Cylindrical Nanoparticles via Crystallization-driven Self-assembly of Biodegradable Block Copolymers
Published on: June 20, 2019
10:54Facile and Efficient Preparation of Tri-component Fluorescent Glycopolymers via RAFT-controlled Polymerization
Published on: June 19, 2015
Related Concept Videos
Radical Chain-Growth Polymerization: Mechanism
Free-Radical Chain Reaction and Polymerization of Alkenes
Cationic Chain-Growth Polymerization: Mechanism
Characteristics and Nomenclature of Copolymers
Radical Chain-Growth Polymerization: Overview
Radical Chain-Growth Polymerization: Chain Branching