Probing Nanoscale Ion Dynamics in Ultrathin Films of Polymerized Ionic Liquids by Broadband Dielectric Spectroscopy

Continuous progress in energy storage and conversion technologies necessitates novel experimental approaches that can provide fundamental insights regarding the impact of reduced dimensions on the functional properties of materials. Here, we demonstrate a nondestructive experimental approach to probe nanoscale ion dynamics in ultrathin films of polymerized 1-vinyl-3-ethylimidazolium bis(trifluoromethylsulfonyl)imide over a broad frequency range spanning over 6 orders of magnitude by broadband dielectric spectroscopy. The approach involves using an electrode configuration with lithographically patterned silica nanostructures, which allow for an air gap between the confined ion conductor and one of the electrodes. We observe that the characteristic rate of ion dynamics significantly slows down with decreasing film thicknesses above the calorimetric glass transition of the bulk polymer. However, the mean rates remain bulk-like at lower temperatures. These results highlight the increasing influence of the polymer/substrate interactions with decreasing film thickness on ion dynamics.