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Updated: Sep 21, 2025

Morphology Control for Fully Printable Organic–Inorganic Bulk-heterojunction Solar Cells Based on a Ti-alkoxide and Semiconducting Polymer
Published on: January 10, 2017
Fully Conjugated Donor-Acceptor Block Copolymers for Organic Photovoltaics via Heck-Mizoroki Coupling
Aiman Rahmanudin1, Liang Yao1, Arvindh Sekar1
1Laboratory for Molecular Engineering of Optoelectronic Nanomaterials, École Polytechnique Fédérale de Lausanne (EPFL), Station 6, Lausanne CH-1015, Switzerland.
Abstract:
The development of facile routes to prepare fully conjugated block copolymers (BCPs) from diverse monomers is an important goal for advancing robust bulk-heterojunction (BHJ) organic photovoltaics (OPVs). Herein we introduce a synthetic strategy for step-growth BCPs employing 1,2-bis(trialkylstannyl)ethene as one monomer, which, in addition to offering improved backbone planarity, directly yields a vinylene-terminated macromonomer suitable for Heck-Mizoroki coupling. The benefits of our strategy, which facilitates the preparation of functionalized macromonomers suitable for BCP synthesis, are demonstrated with a representative BCP based on a diketopyrrolopyrrole (DPP) copolymer coded pBDTTDPP as the donor block and a perylenediimide (PDI) copolymer coded as pPDIV as the acceptor block. Feed ratio optimization affords control over the macromonomer chain-end functionalities and allows for the selective formation of a tri-BCP consisting of pPDIV-b-pBDTTDPP-b-pPDIV, which is employed in a single-component BHJ OPV. Devices achieved a power conversion efficiency of 1.51% after thermal stress at 150 °C compared to 0.02% for a control device consisting of a comparable blend of pBDTTDPP and pPDIV. The difference in performance is ascribed to the morphological stability of the BHJ when using the BCP.
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