Enhancing the dewaterability of waste activated sludge by the combined ascorbic acid and zero-valent iron/persulfate...

In this work, a reducing/chelating agent, ascorbic acid (H₂A) was introduced to the traditional zero-valent iron (Fe⁰)/persulfate (PS) process for waste activated sludge dewatering. The experimental data indicated that H₂A-Fe⁰/PS process significantly enhanced the dewatering performance of sludge and enhanced the oxidation efficiency of Fe⁰-PS treatment. Under optimal conditions, the capillary suction time ratio before and after treatment (CST₀/CST) of H₂A-Fe⁰/PS treated sludge increased by 118% and 31.3% compared with untreated sludge and Fe⁰-PS treated sludge, respectively. The mechanism investigations revealed that the H₂A-Fe⁰/PS induced excellent enhancement for sludge dewaterability could be credited to the reduction and chelating capacity of ascorbic acid. Free radicals including SO₄^•-, O₂^•- and •OH produced in the H₂A-Fe⁰/PS process destroyed proteinaceous components and humic substances in sludge extracellular polymeric substances (EPS), thus reducing the negative charge and water holding capacity of sludge, improving the sludge rheological properties. As a result, the dewatering performance of sludge has been significantly improved.