On the remarkable nonlinear optical properties of natural tomato lycopene

In line with the renewed interest in developing novel Non Linear Optical (NLO) materials, natural Lycopene's NLO Properties are reported for the first time within the scientific literature. Correlated to its 1-D conjugated π-electrons linear conformation, it is shown that natural Lycopene exhibits a significantly elevated 3rd order nonlinearity χ⁽³⁾ as high as 2.65 10^-6 esu, the largest value of any investigated natural phyto-compound so far, including β-carotene. In addition to a saturable absorption, the corresponding observed self-defocusing effect in Lycopene seems to be the result of a thermal nonlinearity. The nonlinear response coupled to the observed fluorescence in the Visible spectral range points to a potential photodynamic therapy application as well as the possibility of engineering of novel hybrid Lycopene based NLO nano-materials.