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Linear Main-Chain 1,2,4-Triazolium Poly(ionic liquid)s: Single-Step Synthesis and Stabilization of Cellulose
Mohamed Yahia1,2, Shilin Mei3, Aji P Mathew1
1Department of Materials and Environmental Chemistry (MMK), Stockholm University, 10691 Stockholm, Sweden.
Abstract:
Linear main-chain 1,2,4-triazolium-based poly(ionic liquid)s (PILs) were synthesized in this contribution. The polymerization process is experimentally very simple and involves only a single-step polycondensation of a commercially available monomer in DMSO as solvent at 120 °C. Their thermal stability and solubility were analyzed in terms of different counteranions. Due to the ease of this synthetic route, it was readily applied to graft onto sulfonated cellulose nanocrystals (CNCs) via a one-step in situ polymerization. The as-synthesized PIL@CNC hybrid colloids exhibit adaptive dispensability in water and organic solvents.
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