Related Experiment Video
Updated: Sep 21, 2025

Facile Synthesis of Worm-like Micelles by Visible Light Mediated Dispersion Polymerization Using Photoredox Catalyst
Published on: June 8, 2016
Preparation of Microporous Organic Polymers via UV-Initiated Radical Copolymerization
Tingting Zhu1, Feifei Xie1, Ting Huang1
1College of Materials and Fujian Provincial Key Laboratory of Materials Genome, Xiamen University, Xiamen, 361005, P.R. China.
Abstract:
UV-initiated radical copolymerization has been successfully applied for the preparation of two kinds of microporous organic polymers (MOPs) based on divinylbenzene (DVB)/bismaleimide (BMI) monomers and DVB/pentaerythritol tetraacrylate (PET4A). The obtained MOPs exhibit high BET surface areas and good CO2 storage performance. The maximum BET surface areas of DVB/BMI and DVB/PET4A are 585 and 887 m2 g-1, respectively. Furthermore, the ester groups embedded on the DVB/PET4A copolymer skeleton can be easily converted into carboxylic groups by hydrolysis and show superior adsorption capacity of 485 mg g-1 toward methylene blue dye. The adoption of this highly efficient polymerization strategy offers the possibility for the economical and continuous preparation of MOPs and demonstrates great potential for industrial application.
More Related Videos
06:49Atom Transfer Radical Polymerization of Functionalized Vinyl Monomers Using Perylene as a Visible Light Photocatalyst
Published on: April 22, 2016
07:01Preparation of Hollow Polystyrene Particles and Microcapsules by Radical Polymerization of Janus Droplets Consisting of Hydrocarbon and Fluorocarbon Oils
Published on: January 25, 2018
Related Concept Videos
Free-Radical Chain Reaction and Polymerization of Alkenes
Radical Chain-Growth Polymerization: Mechanism
Radical Chain-Growth Polymerization: Overview
Olefin Metathesis Polymerization: Ring-Opening Metathesis Polymerization (ROMP)
Cationic Chain-Growth Polymerization: Mechanism
Olefin Metathesis Polymerization: Overview
Ruthenium-based Grubbs catalyst is the most commonly used catalyst for olefin metathesis polymerization. Grubbs catalyst consists...