New nickel-rich ternary carbonate hydroxide two-dimensional porous sheets for high-performance aqueous asymmetric...

Transition metal carbonate hydroxides (M-CHs) are promising candidates for electrode materials in supercapattery, due to their low-cost preparation and high-energy features. However, they also suffer from ionic kinetics bottlenecks without efficient morphological design. Tailoring the chemical compositions and nanostructures of electrode materials to realize high performance is significant for meeting the current demand for electrical energy storage devices. Therefore, we present a simple hydrothermal method for constructing better electrochemically active M-CHs with ternary metal components and hierarchical nanostructures that are assembled by interwoven nanosheets. Benefiting from higher contents of Ni species and superior two-dimensional/three-dimensional (2D/3D) pore structures, the fabricated cobalt-nickel-zinc carbonate hydroxides with Co/Ni/Zn molar ratios of 2:3:1 (CoNiZn-231) delivered the best specific capacity of 1130.8 C g^-1 at 1 A g^-1, decent rate performance (67.2% in 1-10 A g^-1), and excellent cycling performance (92.6% over 10,000 cycles) in comparison with the majority of mono/bimetallic materials. Then, an alkaline hybrid (CoNiZn-231//activated carbon (AC)) device is developed, which shows a high energy density of 31.62 Wh kg^-1 at a power density of 646 W kg^-1 and an excellent capacity retention of 99.27% after 10,000 cycles. Herein, the rational design of trimetallic compositions and hierarchical structures of carbonate hydroxides is described, which provides good choices for the synthesis of high-performance electrode materials in electrochemical energy storage applications.