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An applied magnetic field causes the electrons present in the molecule to circulate, setting up a local diamagnetic current within the molecule. The local diamagnetic current arising from circulating sigma-bonding electrons induces a magnetic field, Blocal that opposes the applied magnetic field, B0. The effective magnetic field experienced by these nuclei is given by the difference between the applied and local magnetic fields in a phenomenon called local diamagnetic shielding. Essentially,...
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Paramagnets are materials with unpaired electrons that possess a finite magnetic moment. In the absence of a magnetic field, these moments are randomly oriented, and thus the net moment is zero. Under an external field, a torque acting on the moments tends to align them along the field's direction. However, the random thermal motion of electrons produces a torque opposite to the external field and tries to disorient the moments. These two competing effects align only a few moments along the...
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An applied magnetic field causes loosely bound π-electrons in organic molecules to circulate, producing a local or induced diamagnetic field over a large spatial volume. As the molecules tumble in solution, the field generated by π-electrons in spherical substituents results in a zero net field. However, the net field generated by π-electrons in non-spherical substituents is not zero. The effect of this induced field depends on the orientation of the molecule with respect to B0,...
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Materials consisting of paired electrons have zero net magnetic moments. However, when these materials are placed under an external magnetic field, the moments opposite to the field are induced. Such materials are called diamagnets. Diamagnetism is the response of the diamagnets when placed in an external magnetic field.
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In linear magnetic materials, like paramagnets and diamagnets, magnetization is proportional to the magnetic field intensity. The constant of proportionality, a dimensionless number, is called magnetic susceptibility. The value of the susceptibility depends on the type of material.
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Magnetic dipoles in magnetic materials are aligned when placed under an external magnetic field. For paramagnets and ferromagnets, dipole alignment occurs in the direction of the magnetic field. However, the dipoles align opposite to the field in the case of diamagnets. This state of magnetic polarization due to the external field is called magnetization. Magnetization is defined as the dipole moment per unit volume. It plays a similar role to polarization in electrostatics.
The vector...
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Magnetic Interacted Interaction Effect in MXene Skeleton: Enhanced Thermal-Generation for Electromagnetic

Mengqiu Huang1, Lei Wang1, Xiao Li1

  • 1Laboratory of Advanced Materials, Shanghai Key Lab of Molecular Catalysis and Innovative Materials, Department of Materials Science, Fudan University, Shanghai, 200438, P. R. China.

Small (Weinheim an Der Bergstrasse, Germany)
|June 8, 2022
PubMed
Summary

A novel magnetized Ti3C2Tx MXene-based film incorporating SrFe12O19 flakes and MWCNTs offers superior electromagnetic interference (EMI) shielding. This flexible material achieves high electrical conductivity and excellent EMI shielding effectiveness, crucial for portable electronics.

Keywords:
MXeneselectromagnetic interference shieldingflexible filmsmagnetic modulation

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Area of Science:

  • Materials Science
  • Nanotechnology
  • Electromagnetics

Background:

  • Portable and wearable electronics require efficient electromagnetic interference (EMI) shielding to mitigate electromagnetic pollution.
  • Existing EMI shielding materials often face limitations in performance, flexibility, or scalability.

Purpose of the Study:

  • To develop a high-efficiency EMI shielding material using a facile filtration approach.
  • To investigate the synergistic effects of Ti3C2Tx MXene, SrFe12O19 flakes, and MWCNTs for enhanced EMI shielding.

Main Methods:

  • Fabrication of a magnetized Ti3C2Tx-based film by assembling hexagonal SrFe12O19 flakes onto a Ti3C2Tx MXene/MWCNT substrate.
  • Utilizing multi-walled carbon nanotubes (MWCNTs) as dispersing agents for MXene and SrFe12O19.
  • Characterization of electrical conductivity and EMI shielding effectiveness in the X-band.

Main Results:

  • The synthesized Ti3C2Tx MXene/MWCNTs/SrFe12O19 film exhibited a high electrical conductivity of 438 S cm⁻¹.
  • Achieved an excellent EMI shielding effectiveness of 62.9 dB at a mere thickness of 40 µm.
  • Demonstrated strong magnetic response and efficient consumption of magnetic field energy via domain wall migration and ferromagnetic resonance.

Conclusions:

  • The developed magnetized MXene-based film offers superior EMI shielding performance due to enhanced magnetic loss and reduced wave reflection.
  • The freestanding and flexible nature of the film makes it suitable for integration into electronic devices.
  • This strategy provides a novel approach for designing advanced EMI shielding materials and expands the applications of MXene-based composites.