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Updated: Sep 20, 2025

Heterogeneous Removal of Water-Soluble Ruthenium Olefin Metathesis Catalyst from Aqueous Media Via Host-Guest Interaction
Published on: August 23, 2018
Demetallation of organometallic and metal-mediated reactions
1Department of Chemistry and FQRNT Centre for Green Chemistry and Catalysis, McGill University, 801 Sherbrooke Street West, Montreal, QC H3A0B8, Canada.
Abstract:
The use of stoichiometric organometallic reagents and stoichiometric metals formed the basis of vast majority of classical reactions for constructing carbon-carbon bonds. The indispensable requirement of stoichiometric metals for such reactions constitutes significant challenges in terms of resource sustainability, operational safety, and chemical-waste management. The recent developments in C-H functionalizations, hydrogenative alkene/alkyne addition to electrophiles, the hydrazone umpolung chemistry, and other emerging fields such as the electrosynthesis and photoredox chemistry provide potential solutions to overcome these inherent challenges.
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