Formation mechanisms of CsPbBr₃/Cs₄PbBr₆ microscale composites assisted with imidazolium cations and their device...

The instability of all-inorganic perovskite nanocrystals (NCs) remains a major challenge to their practical applications in displays and lighting. In order to improve their environmental resistance, highly luminescent CsPbBr₃ NC embedded Cs₄PbBr₆ microcrystals (MCs) have been fabricated by an anti-solvent reprecipitation method with the assistance of 1-alkyl-3-methyl-imidazolium bromides. The heterostructure of the MCs is investigated in detail, and their formation mechanism is discussed in terms of the dissolution-precipitation equilibria and the total energy of variously scaled nanoparticles via density functional theory (DFT) calculations. Although the imidazolium ligands are not directly capping with the inner CsPbBr₃ NCs, they are important to the formation of these MCs. The MCs exhibit better thermal resistance compared to conventional CsPbBr₃ NCs prepared by the hot-injection method. Additionally, a prototype white light-emitting diode (WLED) was fabricated to demonstrate its practical application prospects. Thanks to the narrow emission bands and enhanced stability of the MCs, the WLED shows greater performance compared to bare perovskite NCs, indicating its great potential as a green phosphor in lighting and display applications.