A new zinc-organic framework with 1D channel for constructing a ratiometric Al³⁺-selective sensor and four inputs...

To develop Al³⁺ fluorescent sensor is significant because the abnormal levels of Al³⁺ in environment may pose great threat to human body. Herein, a novel metal-organic framework {Zn(Dpada)(Imdba)·H₂O}_n (Dpada = 3, 6-di(1H-imidazol-1-yl) pyridazine and Imdba = 2, 2'-iminodibenzoic acid), named Zn-MOF, has been architected with one-dimensional channel under hydrothermal conditions. Zn-MOF exhibits good thermal and solvent stability and can also keep structural integrity over the pH range of 5.0 - 9.0. Fluorescent experiments show that Zn-MOF has high selectivity and sensitivity towards Al³⁺ via ratiometric fluorescence signal changes (F_{470 nm}/F_{390 nm}) and the detection limit is evaluated to be 0.69 μM. In addition, Zn-MOF performs good recyclability in sensing of Al³⁺ with at least 5 cycles. Besides, an INHIBIT logic gate has been constructed with chemical ions (Al³⁺, Cr³⁺, Fe³⁺ and Hg²⁺) as input signals and emission ratio (F_{470 nm}/F_{390 nm}) as output signal. Significantly, Zn-MOF can be applied to tracing Al³⁺ using real water samples, presenting great potential in water quality monitoring application.