Room-temperature synthesis and CO₂-gas sensitivity of bismuth oxide nanosensors

Room-temperature (27 °C) synthesis and carbon dioxide (CO₂)-gas-sensor applications of bismuth oxide (Bi₂O₃) nanosensors obtained via a direct and superfast chemical-bath-deposition method (CBD) with different surface areas and structures, i.e., crystallinities and morphologies including a woollen globe, nanosheet, rose-type, and spongy square plate on a glass substrate, are reported. Moprhologies of the Bi₂O₃ nanosensors are tuned through polyethylene glycol, ethylene glycol, and ammonium fluoride surfactants. The crystal structure, type of crystallinity, and surface appearance are determined from the X-ray diffraction patterns, X-ray photoelectron spectroscopy spectra, and high-resolution transmission electron microscopy images. The room-temperature gas-sensor applications of these Bi₂O₃ nanosensors for H₂, H₂S, NO₂, SO_2, and CO₂ gases are monitored from 10 to 100 ppm concentrations, wherein Bi₂O₃ nanosensors of different physical properties demonstrate better performance and response/recovery time measurement for CO₂ gas than those for the other target gases employed. Among various sensor morphologies, the nanosheet-type Bi₂O₃ sensor has exhibited at 100 ppm concentration of CO₂ gas, a 179% response, 132 s response time, and 82 s recovery time at room-temperature, which is credited to its unique surface morphology, high surface area, and least charge transfer resistance. This suggests that the importance of the surface morphology, surface area, and crystallinity of the Bi₂O₃ nanosensors used for designing room-temperature operable CO₂ gas sensors for commercial benefits.