Optimization and assessment of an electrochemical advanced oxidation system for synthetic stormwater treatment

Electrochemical advanced oxidation processes (eAOPs) such as the current advanced oxidation system (AOS) are a type of electrochemical wastewater treatment that creates oxidative species, such as iodide species, chloride species, and hydroxyl radicals, that can treat even the most recalcitrant contaminants. It is important to determine the concentrations and locations of oxidative species in eAOPs for optimization of the wastewater treatment process. In this study, a spectrophotometric methodology was used to determine concentrations of iodide and chloride oxidative species (starting at 10, 25, and 50 ppm) within an AOS under various input voltages (6, 12, and 24 V). Overall, it was found that iodate and chlorite were the dominant species created in their respective treatments. Additionally, the concentration of iodide oxidative species increased with increasing voltage, whereas the chloride species decreased with increasing voltage. The optimal conditions for the efficient creation of AOS oxidative species were 12 V and 10 ppm potassium iodide and 6 V and 10 ppm sodium chloride, respectively. In addition, the use of iodide is recommended for wastewater treatment using the AOS to effectively create oxidative species. Following optimization, the AOS performance was tested for synthetic stormwater. Results indicated that the AOS performed well for reduction of Escherichia coli; however, reduction of other contaminants was inconsistent as would be expected given the AOS was optimized for disinfection, not decontamination. Further AOS optimization for decontamination would be expected to result in improved decontamination performance.