Tough and Antifreezing MXene@Au Hydrogel for Low-Temperature Trimethylamine Gas Sensing

Trimethylamine (TMA) is one of the important chemical indexes to judge the freshness of marine fish. It is necessary to develop a low temperature TMA sensor to help the monitoring and prediction of the quality of marine fish in cold chain. Herein, a flexible low temperature TMA gas sensor featuring antifreezing and superior mechanical properties was developed based on the Au nanoparticle-modified MXene (MXene@Au) composite. MXene@Au was synthesized and then polymerized with a hydrogel composed of acrylamide (AM), N,N'-methylenebisacrylamide (BIS), sodium carboxymethyl cellulose (CMC), and EG, and the resultant MXene@Au hydrogel was found to exhibit excellent antifreezing performance even at extremely low temperature as well as high tensile strength, ultrastretchability, and toughness, which enabled an efficient gas sensing platform for TMA detection at low temperature. The TMA sensing properties of the flexible MXene@Au DN hydrogel sensor at 25 °C and a low temperature of 0 °C were studied, and a linear relationship between TMA sensitivity and concentration was built. The excellent sensing properties were maintained even under deformation. The application of the MXene@Au DN hydrogel sensor in detection of fish freshness at 0 °C was investigated. The result indicated the potential application of the flexible MXene@Au DN hydrogel gas sensor in dynamic quality monitoring and prediction of marine fish products during its transportation and storage in the cold chain.