Vanadium recovery by electrodialysis using polymer inclusion membranes

Industrial applications and environmental awareness recently prompted vanadium recovery spell from secondary resources. In this work, a polymer inclusion membrane containing trioctylmethylammonium chloride as carrier was successfully employed in electrodialysis for vanadium recovery from acidic sulfate solutions. The permeability coefficient of V(V) increased from 0.29 µm·s^-1 (without electric field) to 4.10 µm·s^-1 (with the 20 mA·cm^-2 current density)_. The transport performance of VO₂SO₄^-, which was the predominant species containing V(V) in the acidic region (pH <3), was influenced by the aqueous pH value and sulfate concentration. Under an electric field, a low concentrated H₂SO₄ solution (0.2 M) effectively stripped V(V) from the membranes, avoiding the requirement of a highly concentrated H₂SO₄ without electric field. Under the optimum conditions, the permeability coefficient and flux reached 6.80 µm·s^-1 and 13.34 µmol·m^-2·s^-1, respectively. High selectivity was observed for the separation of V(V) and Mo(VI) from mixed solutions of Co (II), Ni (II), Mn (II), and Al (III). Additionally, the separation between Mo(VI) and V(V) was further improved by adjusting the acidity of the stripping solution. The V(V) selectivity for the resulting membrane was higher than that of commercial anion exchange membranes.