Shrimp waste-derived porous carbon adsorbent: Performance, mechanism, and application of machine learning

Aquaculture generates significant amount of processing wastes (more than 500 million pounds annually in the United States), the bulk of which ends up in the environment or is used in animal feed. Proper utilization of shrimp waste can increase their economic value and divert them from landfills. In this study, shrimp waste was converted to a porous carbon (named SPC) via direct pyrolysis and activation. SPC was characterized, and its performance for adsorbing ciprofloxacin from simulated water, natural waters, and wastewater was benchmarked against a commercial powdered activated carbon (PAC). The surface area of SPC (2262 m²/g) exceeded that of PAC (984 m²/g) due to abundance of micropores and mesopores. The adsorption of ciprofloxacin by SPC was thermodynamically spontaneous (ΔG = -19 kJ/mol) and fast (k₁ = 1.05/min) at 25 °C. The capacity of SPC for ciprofloxacin (442 mg/g) was higher than that of PAC (181 mg/g). SPC also efficiently and simultaneously removed low concentrations (200 µg/L) of ciprofloxacin, long-chain per- and polyfluoroalkyl substances (PFAS), and Cu ions from water. An artificial neural network function was derived to predict ciprofloxacin adsorption and identify the relative contribution of each input parameter. This study demonstrates a sustainable and commercially viable pathway to reuse shrimp processing wastes.