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Flow-Switched Bistability in a Colloidal Gel with Non-Brownian Grains
Yujie Jiang1, Soichiro Makino1, John R Royer1
1SUPA, School of Physics and Astronomy, The University of Edinburgh, King's Buildings, Peter Guthrie Tait Road, Edinburgh EH9 3FD, United Kingdom.
Abstract:
We show that mixing a colloidal gel with larger, non-Brownian grains generates novel flow-switched bistability. Using a combination of confocal microscopy and rheology, we find that prolonged moderate shear results in liquefaction by collapsing the gel into disjoint globules, whereas fast shear gives rise to a yield-stress gel with granular inclusions upon flow cessation. We map out the state diagram of this new "mechanorheological material" with varying granular content and demonstrate that its behavior is also found in separate mixture using different particles and solvents.
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