The noble metals M (M = Pd, Ag, Au) decorated CeO₂catalysts derived from solution combustion method for efficient...

The noble metal nanoparticles have attracted attention due to their excellent catalytic performance for CO oxidation at low temperatures. M-CeO₂(M = Pd, Ag, Au) catalysts with different atomic ratios of M/Ce were deposited via solution combustion method. Among them, 3 at% Pd-CeO₂, 5 at% Ag-CeO₂and 1 at% Au-CeO₂catalysts have better catalytic performances. Especially, 5 at% Ag-CeO₂catalyst shows better low-temperature CO oxidation performance. The catalytic activity for CO oxidation follows the follows the following sequence: 5 at% Ag-CeO₂(T₅₀ = 69 °C) > 3 at% Pd-CeO₂(T₅₀ = 99 °C) >1 at% Au-CeO₂(T₅₀ = 115 °C). Meanwhile, the catalysts are characterized by means of powder x-ray diffraction, scanning electron microscope, transmission electron microscopy, Raman spectroscopy, x-ray photoelectron spectroscopy, Brunauer-Emmett-Teller and H₂-TPR. The characterization results show that the 5 at% Ag-CeO₂catalyst has excellent catalytic activity due to the good dispersion of Ag nanoparticles, the specific surface area of the material, and the reduction catalyst between different valence ions. Moreover, the surface of the catalyst enhances the mutual synergy, effectively promotes the generation of oxygen vacancies, and increases the active oxygen content of the catalyst surface. Finally, the catalytic mechanism of M-CeO₂catalysts is summarized.