Efficient activation of persulfate by C@Fe₃O₄ in visible-light for tetracycline degradation

A C@Fe₃O₄ material, Fe₃O₄ coated with carbon, was prepared by a simple one-pot hydrothermal method. The C@Fe₃O₄ material was investigated with persulfate (PS) and light to degrade tetracycline (TC) as a function of pH, aeration conditions and quenching. Experimental results suggest that TC was effectively degraded in the C@Fe₃O₄/PS/Vis system. In addition, due to the availability of different main active species in this catalytic system, TC degradation was possible under both strong acid and strong alkali pH conditions. The presence of dissolved oxygen can also generate oxygen-active species, such as superoxide radicals (O₂•^-) and singlet oxygen (¹O₂), to decompose TC organic matter in solution. Simply put, C@Fe₃O₄/PS/Vis catalytic system removed pollutants by the formation of O₂•^-, ¹O₂, hydroxyl radicals (•OH) and sulfate radicals (SO₄•^-) species for degrading TC. In addition, the stability of the C@Fe₃O₄ material was found to be outstanding.