Robust Oxygen Reduction Electrocatalysis Enabled by Platinum Rooted on Molybdenum Nitride Microrods

Robust oxygen reduction electrocatalysis is central to renewable fuel cells and metal-air batteries. Herein, Pt nanoparticles (NPs) rooted on porous molybdenum nitride microrods (Pt/Mo₂N MRs) are rationally constructed toward the oxygen reduction reaction (ORR). Owing to the desired composition with strong electronic metal-support interactions (EMSIs) and a porous one-dimensional structure supporting ultrafine NPs, the developed Pt/Mo₂N MRs possess much higher ORR mass and specific activities than commercial Pt/C. In situ Raman and density functional theory calculations reveal that the EMSI weakens the adsorption of intermediates over Pt/Mo₂N MRs via an associative mechanism. Moreover, the porous Mo₂N support stabilizes these high activities. Impressively, a homemade zinc-air battery driven by Pt/Mo₂N MRs delivers excellent performance including a peak power density of 167 mW cm^-2 and a high rate capability that ranged from 5 to 50 mA cm^-2. This work highlights the role of EMSI in promoting robust ORR electrocatalysis, thus providing a promising approach for efficient and robust cathode materials for advanced metal-air batteries.