Amorphous Co@TiO₂ heterojunctions: A high-performance and stable catalyst for the efficient degradation of...

Persulfate-based advanced oxidation processes (AOPs) cannot easily achieve the efficient degradation of persistent organic pollutants (POPs) with high stability. In this study, a simple in situ precipitation method was used to prepare an amorphous Co@TiO₂ heterojunction catalyst. The deposition of Co oxide on TiO₂, which is relatively nontoxic, efficiently activated peroxymonosulfate (PMS) to degrade sulfamethazine (SMT) and reduce the leaching of Co ions (0.915%). A catalytic system prepared using 0.3 g L^-1 Co@TiO₂ and 0.5 g L^-1 PMS could degrade SMT within 30 min with a degradation rate of 95.8%. Co@TiO₂ could activate PMS over a wide pH range (5.00-9.00) to efficiently degrade other antibiotics and dyes. Radical-capture experiments and electron paramagnetic resonance analysis suggested that SMT degradation occurs through a combination of the free radical and non-radical pathways, in which singlet ¹O₂ played a major role. Owing to the novelty of the proposed composite materials, the degradation path of SMT, which was determined through liquid chromatography-mass spectrometry, differed from that reported previously. This study provides not only an advanced and renewable catalyst for SMT degradation but also a feasible strategy for designing materials for AOPs.