Peroxymonosulfate activation through ferromagnetic bimetallic spinel sulfide composite (Fe₃O₄/NiCo₂S₄) for organic...

Spinel sulfides are a good candidate as heterogeneous catalysts for wastewater treatment through peroxymonosulfate (PMS) activation. In this paper, magnetic Fe₃O₄/NiCo₂S₄ composite was successfully synthesized by hydrothermal method. Catalyst screening displayed that the composite catalyst with a Fe₃O₄:NiCo₂S₄ molar ratio of 1:3 (i.e.,0.33-Fe₃O₄/NiCo₂S₄) is the most optimal. The results showed that 0.33-Fe₃O₄/NiCo₂S₄ composite catalyst had superior catalytic activity, achieving 99.8%,65.1% and 40.7% of RhB, COD and TOC removals within 30 min with 180 m g/L PMS and 75 mg/L catalyst. We proposed a potential catalytic mechanism of PMS activation by Fe₃O₄/NiCo₂S₄ in two aspects. On the one hand, sulfur species such as S^2- and S₂^2- enhance the Co³⁺/Co²⁺, Ni³⁺/Ni²⁺ and Fe³⁺/Fe²⁺ cycles on Fe₃O₄/NiCo₂S₄ surface. On the other hand, there is the synergistic effect of Co³⁺/Co²⁺, Ni³⁺/Ni²⁺ and Fe³⁺/Fe²⁺ cycles in activating PMS. Overall, owing to its excellent catalytic activity, reusability, and easy recovery, Fe₃O₄/NiCo₂S₄ is a potentially useful catalyst for remediation of contaminated water.