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Updated: Sep 4, 2025

Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives
Published on: February 7, 2017
BN-Embedded V-Shaped Polycyclic Aromatic Hydrocarbons Exhibiting Tunable Molecular Packing and Supramolecular
Ning Zhang1, Jiangyu Zhu1, Dongyue An1
1Department of Materials Science, Fudan University, Shanghai 200433, People's Republic of China.
Abstract:
Three novel BN-embedded V-shaped polycyclic aromatic hydrocarbons with different π-conjugation lengths were designed and successfully synthesized. Their single-crystal structures were confirmed by X-ray crystallographic analysis, and it is found that the molecular stacking structure can be effectively tuned by extending the length of π conjugation. Meanwhile, owing to the unique V-shaped molecular geometry, they exhibit moderate host-guest supramolecular interactions with both fullerenes C60 and C70.
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