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Updated: Sep 4, 2025

Atom Transfer Radical Polymerization of Functionalized Vinyl Monomers Using Perylene as a Visible Light Photocatalyst
Published on: April 22, 2016
Visible-Light-Induced, Palladium-Catalyzed Annulation of 1,3-Dienes to Construct Vinyl N-Heterocycles
Yu Zheng1, Weidong Lu1, Zhenzhen Xie1
1College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, Hunan, P. R. China.
Abstract:
Herein, a photoinduced palladium-catalyzed annulation of 1,3-dienes with bifunctional halognated alkylamines has been developed, offering a facile route to access a broad range of vinylpyrrolidines. The reactivity profile of this protocol was able to be readily manipulated to assemble vinylpyrrolidine and vinlysilaazacycle. Remarkably, the utility of this strategy was further illustrated in the construction of complex and biologically important molecules as well as the diversity-oriented transformations of the resulting product.
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