Efficient Separation of Trace SO₂ from SO₂/CO₂/N₂ Mixtures in a Th-Based MOF

The emission of sulfur dioxide (SO₂) from flue gases is harmful since trace SO₂ impairs human health and the natural environment. Therefore, developing new metal organic frameworks (MOFs) to capture this toxic molecule is of great importance in flue gas desulfurization. In this work, we synthesized a new MOF, namely, ECUT-Th-60, which consists of two distinct channels (3.0 Å × 4.1 Å and 2.3 Å × 4.8 Å). It shows SO₂ uptakes of around 2.5 mmol/g at 0.1 kPa and 3.35 mmol/g at 1 bar, which are higher than those of CO₂ and N₂ under identical conditions. Both simulated and experimental breakthrough tests proved that ECUT-Th-60 can separate trace SO₂ from SO₂/CO₂ mixtures. Impressively, complete separation of SO₂ from SO₂/CO₂/N₂ mixtures under both dry and humid conditions was also proved in ECUT-Th-60, predicting its potential application in flue gas desulfurization.