Highly Dispersion Cu₂O QDs Decorated Bi₂WO₆ S-Scheme Heterojunction for Enhanced Photocatalytic Water Oxidation

Developing suitable photocatalysts for the oxygen evolution reaction (OER) is still a challenging issue for efficient water splitting due to the high requirements to create a significant impact on water splitting reaction kinetics. Herein, n-type Bi₂WO₆ with flower-like hierarchical structure and p-type Cu₂O quantum dots (QDs) are coupled together to construct an efficient S-scheme heterojunction, which could enhance the migration efficiency of photogenerated charge carriers. The electrochemical properties are investigated to explore the transportation features and donor density of charge carriers in the S-scheme heterojunction system. Meanwhile, the as-prepared S-scheme heterojunction presents improved photocatalytic activity towards water oxidation in comparison with the sole Bi₂WO₆ and Cu₂O QDs systems under simulated solar light irradiation. Moreover, the initial O₂ evolution rate of the Cu₂O QDs/Bi₂WO₆ heterojunction system is 2.3 and 9.7 fold that of sole Bi₂WO₆ and Cu₂O QDs systems, respectively.