Tribological Behavior of Reduced Graphene Oxide-Al₂O₃ Nanofluid: Interaction among Testing Force, Rotational Speed...

The tribological properties of nanofluids are influenced by multiple factors, and the interrelationships among the factors are deserving of further attention. In this paper, response surface methodology (RSM) was used to study the tribological behavior of reduced graphene oxide-Al₂O₃ (rGO-Al₂O₃) nanofluid. The interaction effects of testing force, rotational speed and nanoparticle concentration on the friction coefficient (μ), wear rate (W_r) and surface roughness (R_a) of steel disks were investigated via the analysis of variance. It was confirmed that all the three input variables were significant for μ and W_r values, while testing force, nanoparticle concentration and its interaction with testing force and rotational speed were identified as significant parameters for R_a value. According to regression quadratic models, the optimized response values were 0.088, 2.35 × 10^-7 mm³·N^-1·m^-1 and 0.832 μm for μ, W_r and R_a, which were in good agreement with the actual validation experiment values. The tribological results show that 0.20% was the optimum mass concentration which exhibited excellent lubrication performance. Compared to the base fluid, μ, W_r and R_a values had a reduction of approximately 45.6%, 90.3% and 56.0%. Tribochemical reactions occurred during the friction process, and a tribofilm with a thickness of approximately 20 nm was generated on the worn surface, consisting of nanoparticle fragments (rGO and Al₂O₃) and metal oxides (Fe₂O₃ and FeO) with self-lubrication properties.