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Van der Waals Equation01:10

Van der Waals Equation

4.5K
The ideal gas law is an approximation that works well at high temperatures and low pressures. The van der Waals equation of state (named after the Dutch physicist Johannes van der Waals, 1837−1923) improves it by considering two factors.
First, the attractive forces between molecules, which are stronger at higher densities and reduce the pressure, are considered by adding to the pressure a term equal to the square of the molar density multiplied by a positive coefficient a. Second, the volume...
4.5K
Van der Waals Interactions01:24

Van der Waals Interactions

65.5K
Atoms and molecules interact with each other through intermolecular forces. These electrostatic forces arise from attractive or repulsive interactions between particles with permanent, partial, or temporary charges. The intermolecular forces between neutral atoms and molecules are ion–dipole, dipole–dipole, and dispersion forces, collectively known as van der Waals forces.
65.5K
Real Gases: Effects of Intermolecular Forces and Molecular Volume Deriving Van der Waals Equation04:01

Real Gases: Effects of Intermolecular Forces and Molecular Volume Deriving Van der Waals Equation

35.2K
Thus far, the ideal gas law, PV = nRT, has been applied to a variety of different types of problems, ranging from reaction stoichiometry and empirical and molecular formula problems to determining the density and molar mass of a gas. However, the behavior of a gas is often non-ideal, meaning that the observed relationships between its pressure, volume, and temperature are not accurately described by the gas laws. 
35.2K
Superconductor01:24

Superconductor

1.2K
A substance that reaches superconductivity, a state in which magnetic fields cannot penetrate, and there is no electrical resistance, is referred to as a superconductor. In 1911, Heike Kamerlingh Onnes of Leiden University, a Dutch physicist, observed a relation between the temperature and the resistance of the element mercury. The mercury sample was then cooled in liquid helium to study the linear dependence of resistance on temperature. It was observed that, as the temperature decreased, the...
1.2K
Theory of Metallic Conduction01:17

Theory of Metallic Conduction

1.4K
The conduction of free electrons inside a conductor is best described by quantum mechanics. However, a classical model makes predictions close to the results of quantum mechanics. It is called the theory of metallic conduction.
In this theory, Newton's second law of motion is used to determine the acceleration of an electron in the presence of an applied electric field. Then, its velocity is expressed via this acceleration.
An electron moves through the crystal, containing positive ions,...
1.4K
Types Of Superconductors01:28

Types Of Superconductors

1.1K
A superconductor is a substance that offers zero resistance to the electric current when it drops below a critical temperature. Zero resistance is not the only interesting phenomenon as materials reach their transition temperatures. A second effect is the exclusion of magnetic fields. This is known as the Meissner effect. A light, permanent magnet placed over a superconducting sample will levitate in a stable position above the superconductor. High-speed trains that levitate on strong...
1.1K

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Related Experiment Video

Updated: Sep 2, 2025

Scalable Quantum Integrated Circuits on Superconducting Two-Dimensional Electron Gas Platform
05:39

Scalable Quantum Integrated Circuits on Superconducting Two-Dimensional Electron Gas Platform

Published on: August 2, 2019

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Intercalate Superconductivity and van der Waals Equation.

Shermane M Benjamin1

  • 1The National High Magnetic Field Laboratory, 1800 E. Paul Dirac Drive, Tallahassee, Florida 32310, United States.

ACS Materials Au
|August 5, 2022
PubMed
Summary
This summary is machine-generated.

This study reveals a new method to estimate the superconducting energy gap in intercalated compounds using physical properties like intercalant concentration and transition temperature. The van der Waals attractive energy directly correlates with the BCS energy gap.

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Area of Science:

  • Condensed Matter Physics
  • Materials Science

Background:

  • Superconductivity in intercalated compounds remains an active area of research.
  • Understanding the fundamental mechanisms governing superconductivity is crucial for material design.

Purpose of the Study:

  • To investigate superconductivity in single-element intercalated compounds using the van der Waals equation.
  • To establish a relationship between the van der Waals attractive energy and the superconducting energy gap.

Main Methods:

  • Utilized the van der Waals equation to analyze superconductivity in Cu$_{}$TiSe$_{2}$ and YBa$_{2}$Cu$_{3}$O$_{6+}$ compounds.
  • Calculated the van der Waals term (attractive energy per particle) from experimental transition temperature plots.
  • Correlated the attractive energy per intercalant valence electron with the BCS energy gap.

Main Results:

  • Demonstrated that twice the attractive energy per intercalant valence electron (2aN$_{val}$/V$_{unit}$) equals the BCS energy gap (Δ).
  • Established a direct link between real-space physical properties and the superconducting energy gap.
  • Identified intercalant concentration, transition temperature, and intercalant valence electrons per unit cell volume as key physical properties.

Conclusions:

  • The study provides a novel method to estimate the energy gap of superconducting intercalated insulators and semiconductors.
  • This approach allows for gap estimation directly from measurable physical properties and applied pressure.
  • Offers new insights into the nature of superconductivity in van der Waals materials.