Ba₃HgGa₂S₇: A Zero-Dimensional Quaternary Sulfide Featuring a Unique [Hg₂Ga₄S₁₄]^12- String and Exhibiting a High...

The discovery of new types of metal sulfides is attractive because of their rich structures and diverse physical properties. Here, a novel quaternary sulfide, Ba₃HgGa₂S₇ (BHGS), is obtained by a solid-state reaction at 1123 K. It crystallizes in the monoclinic space group P2₁/c, and its zero-dimensional structure features two seesaw-like HgS₂ units and four GaS₄ tetrahedra, constructing a unique [Hg₂Ga₄S₁₄]^12- string. BHGS has a wide band gap of 3.64 eV and a large birefringence of 0.09 at 2100 nm. Specifically, BHGS exhibits a remarkable photocurrent response. This work may be extended to a new family of AE₃M^IIM^III₂Q₇ (AE = Mg, Ca, Sr, Ba; M^II = Zn, Cd, Hg; M^III = Al, Ga, In; Q = S, Se) chalcogenides.