Polarization improvement of perovskite nanowire composite films by mechanical stretching method

Perovskite nanowires (NWs) have attracted considerable interest because of their excellent polarization properties. In this work, we first synthesized colloidal lead halide CsPbBr₃NWs with suitable lengths and excellent polarization performance by the method of the thermal injection. By embedding the NWs in polyvinyl alcohol (PVA) to prepare practical a polymer composite and combining it with the mechanical stretching method, we achieved films with higher polarizing properties. The optimized stretched composite film achieved a polarization degree of 0.4992, which is superior to that of the unstretched one. The stretched PVA molecules are arranged in a straight line, which absorbs the polarized light parallel to the alignment direction, and only allows the polarized light in the vertical direction to pass through. Therefore, the arrangement of the spin-coated NWs combined with the arrangement direction of the PVA molecules led to an improvement in the polarization performance of the composite film. The NWs-PVA-stretched composite films will show important application value in the manufacture of next-generation polarization-sensitive optoelectronic devices and other fields.